A 1 molar aqueous solution of magnesium nitrate is $40 \%$ dissociated at 298 K . Calculate the osmotic pressure of the solution. $\left(R=0.0821 \mathrm{~L} \mathrm{~atm} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}\right)$
20.5 atm
44.04 atm
4.11 atm
2.87 atm
$$ \text { The product } Z \text { formed in the given reaction is } $$





In a cyclic $p V$ process forming $A$ square loop from $(p=1 \mathrm{~atm}, V=2 \mathrm{~L})$ to $(p=3 \mathrm{~atm}$, $V=4 \mathrm{~L})$, Then, the net heat absorbed by the gas is

$2 \mathrm{~L} \cdot \mathrm{~atm}$
$4 \mathrm{~L} \cdot \mathrm{~atm}$
$8 \mathrm{~L} \cdot \mathrm{~atm}$
$6 \mathrm{~L} \cdot \mathrm{~atm}$
Balance the following redox reaction in acidic medium and determine the stoichiometric coefficient of $\mathrm{H}_2 \mathrm{O}$ in the final balanced equation.
$$ \mathrm{MnO}_4^{-}(a q)+\mathrm{Fe}^{2+}(a q) \longrightarrow \mathrm{Mn}^{2+}(a q)+\mathrm{Fe}^{3+}(a q) $$
2
4
6
8
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