1
BITSAT 2020
MCQ (Single Correct Answer)
+3
-1

In qualitative analysis when H2S is passed through an aqueous solution of salt acidified with dilute HCl, a black ppt. is obtained. On boiling the precipitate with dil. HNO3, it forms a solution of blue colour. Addition of excess of aqueous solution of NH3 to this solution gives

A
deep blue ppt. of Cu(OH)2
B
deep blue solution of [Cu(NH3)4]2+
C
deep blue solution of Cu(NO3)2
D
deep blue solution of Cu(OH)2 . Cu(NO3)2
2
BITSAT 2020
MCQ (Single Correct Answer)
+3
-1

Titration of 0.1467 g of primary standard Na2C2O4 required 28.85 mL of KMnO4

solution. Calculate the molar concentration of KMnO4 solution.
A
0.01518 M
B
0.001518 M
C
0.15180 M
D
1.5180 M
3
BITSAT 2020
MCQ (Single Correct Answer)
+3
-1

Identify the incorrect statement regarding the complex [Cr(NH3)6]Cl3.

A
The complex involves d2sp3 hybridisation and its octahedral in shape.
B
The complex is paramagnetic.
C
The complex is an outer orbital complex.
D
The complex gives white precipitate with silver nitrate solution.
4
BITSAT 2020
MCQ (Single Correct Answer)
+3
-1

Sulphuric acid is a dibasic acid. It ionises in two stages and hence has two dissociation constants Ka1 and Ka2. Which of the following is the correct observation regarding Ka1 and Ka2 ?

A
Ka1 > Ka2
B
Ka1 < Ka2
C
Ka1 = Ka2
D
Ka1 = 1.2 $$\times$$ 10$$-$$2, Ka2 > 10
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