Identify the air pollutant which in high concentration leads to stiffness of flower buds?

The number of primary $\left(1^{\circ}\right)$, secondary $\left(2^{\circ}\right)$ and tertiary $\left(3^{\circ}\right)$ alcohols possible for the formula $\mathrm{C}_5 \mathrm{H}_{12} \mathrm{O}$ respectively are

The catalyst used for the isomerisation of $n$-alkanes to branched chain alkanes is

An element crystallises in bcc lattice. The atomic radius of the element is $2.598 \mathop {\rm{A}}\limits^{\rm{o}}$. What is the volume (in $\mathrm{cm}^3$ ) of one unit cell?