At STP, a closed vessel contains I mole each of He and $\mathrm{CH}_4$. Through a small hole, 2 L of He and LL of $\mathrm{CH}_4 \mathrm{WHS}$ escaped from vessel in ' $t$ ' minutes. What are the mole fractions of He and $\mathrm{CH}_4$ respectively remaining in the vessel? ( Assume He and $\mathrm{CH}_4$ as ideal gases. At STP one mole of an ideal gas occupies 22.4 L of volume.)
What is the enthalpy change (in J ) for converting 98 of $\mathrm{H}_2 \mathrm{O}(t)+10^{\circ} \mathrm{C}$ to $\mathrm{H}_2 \mathrm{O}(l)$ at $+20^{\circ} \mathrm{C}$ ?
$$ \left(C_p\left(\mathrm{H}_2 \mathrm{O}(\eta)\right)=75 \mathrm{Jmol}^{-1} \mathrm{~K}^{-1}\right) $$
(density of $\mathrm{H}_2 \mathrm{O}(l)=1 \mathrm{gmL}^{-1}{ }^{})$
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