Give the structure of the major product expected from the following reactions:

(a) Reaction of ethanal with methyl-magnesium bromide followed by hydrolysis.

(b) Hydration of But-1-ene in the presence of dilute sulphuric acid.

(c) Reaction of phenol with bromine water.

Draw the structures of major product(s) in each of the following reactions:

Calculate the emf of the following cell:

$$\mathrm{Ni}(\mathrm{~s})+2 \mathrm{Ag}^{+}(0.01 \mathrm{M}) \rightarrow \mathrm{Ni}^{2+}(0.1 \mathrm{M})+2 \mathrm{Ag}(\mathrm{~s})$$

Given that $\mathrm{E}_{\text {cell }}^{\circ}=1.05 \mathrm{~V}, \log 10=1$

Account for the following:

(a) Haloalkanes react with AgCN to form isocyanide as main product.

(b) Allyl chloride shows high reactivity towards $\mathrm{S}_{\mathrm{N}} 1$ reaction.

(c) Haloarenes are extremely less reactive towards nucleophilic substitution reactions.