For the pair phenol and cyclohexanol, answer the following

(a) Why is phenol more acidic than cyclohexanol?

(b) Give one chemical test to distinguish between the two.

(a) (i) Draw the zwitter ion structure for sulphanilic acid.

(ii) How can the activating effect of $$-\mathrm{NH}_2$$ group in aniline be controlled?

OR

(b) (i) Complete the reaction with the main product formed:

(ii) Convert Bromoethane to Propanamine.

Give the reaction of glucose with hydrogen cyanide. Presence of which group is confirmed by this reaction?

(a) For the reaction

$$2 \mathrm{~N}_2 \mathrm{O}_{5(\mathrm{~g})} \rightarrow 4 \mathrm{NO}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})} \text { at } 318 \mathrm{~K}$$

Calculate the rate of reaction if rate of disappearance of $$\mathrm{N}_2 \mathrm{O}_{5(\mathrm{~g})}$$ is $$1.4 \times 10^{-3} \mathrm{~m} \mathrm{~s}^{-1}$$.

(b) For a first order reaction derive the relationship $$\mathbf{t}_{99 \%}=\mathbf{2} \mathbf{t}_{90 \%}$$