1
CBSE 12th Chemistry Delhi Set 1 - 2023
MCQ (Single Correct Answer)
+1
-0

A voltaic cell is made by connecting two half cells represented by half equations below:

$$\begin{aligned} & \mathrm{Sn}_{(a q)}^{2+}+2 \mathrm{e}^{-} \rightarrow \mathrm{Sn}_{(\mathrm{s})} \mathrm{E}^{\mathrm{o}}=-0.14 \mathrm{~V} \\ & \mathrm{Fe}^{3+}{ }_{(\mathrm{aq})}+\mathrm{e}^{-} \rightarrow \mathrm{Fe}^{2+}{ }_{(\mathrm{aq})} \mathrm{E}^{\mathrm{o}}=+0.77 \mathrm{~V} \end{aligned}$$

Which statement is correct about this voltaic cell?

A
$$\mathrm{Fe}^{2+}$$ is oxidised and the voltage of the cell is $$-0.91 \mathrm{~V}$$
B
$$\mathrm{Sn}$$ is oxidised and the voltage of the cell is $$0.91 \mathrm{~V}$$
C
$$\mathrm{Fe}^{2+}$$ is oxidised and the voltage of the cell is $$0.91 \mathrm{~V}$$
D
$$\mathrm{Sn}$$ is oxidised and the voltage of the cell is $$0.63 \mathrm{~V}$$
2
CBSE 12th Chemistry Delhi Set 1 - 2023
MCQ (Single Correct Answer)
+1
-0

Four half reactions I to IV are shown below:

I. $$2 \mathrm{Cl}^{-} \rightarrow \mathrm{Cl}_2+2 \mathrm{e}^{-}$$

II. $$4 \mathrm{OH}^{-} \rightarrow \mathrm{O}_2+2 \mathrm{H}_2 \mathrm{O}+2 \mathrm{e}^{-}$$

III. $$\mathrm{Na}^{+}+\mathrm{e}^{-} \rightarrow \mathrm{Na}$$

IV. $$2 \mathrm{H}^{+}+2 \mathrm{e}^{-} \rightarrow \mathrm{H}_2$$

Which two of these reactions are most likely to occur when concentrated brine is electrolysed?

A
I and III
B
I and IV
C
II and III
D
II and IV
3
CBSE 12th Chemistry Delhi Set 1 - 2023
MCQ (Single Correct Answer)
+1
-0

Which property of transition metals enables them to behave as catalysts?

A
High melting point
B
High ionisation enthalpy
C
Alloy formation
D
Variable oxidation states
4
CBSE 12th Chemistry Delhi Set 1 - 2023
MCQ (Single Correct Answer)
+1
-0

In the two tetrahedral structures of dichromate ion

A
$$4 \mathrm{Cr}-\mathrm{O}$$ bonds are equivalent in length.
B
$$6 \mathrm{Cr}-\mathrm{O}$$ bonds are equivalent in length.
C
All $$\mathrm{Cr}-\mathrm{O}$$ bonds are equivalent in length.
D
All $$\mathrm{Cr}-\mathrm{O}$$ bonds are non-equivalent.
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