(a) (i) What should be the signs (positive/ negative) for $$\mathrm{E}_{\text {Cell }}^0$$ and $$\Delta \mathrm{G}^0$$ for a spontaneous redox reaction occurring under standard conditions?

(ii) State Faraday's first law of electrolysis.

OR

(b) Calculate the emf of the following cell at $$298 \mathrm{~K}$$ :

$$\begin{aligned} & \mathrm{Fe}_{(\mathrm{s})}\left|\mathrm{Fe}^{2+}(0.01 \mathrm{M}) \| \mathrm{H}_{(1 \mathrm{M})}^{+}\right| \mathrm{H}_{2(\mathrm{~g})}(1 \mathrm{bar}), \mathrm{Pt}_{(\mathrm{s})} \\ & \text { Given } \mathrm{E}_{\mathrm{Cen}}^0=0.44 \mathrm{~V}. \end{aligned}$$

What happens to the rate constant $$k$$ and activation energy $$E_a$$ as the temperature of a chemical reaction is increased? Justify.

(a) Which of the following species cannot act as a ligand? Give reason.

$$\mathrm{OH}^{-}, \mathrm{NH}_4^{+}, \mathrm{CH}_3 \mathrm{NH}_2, \mathrm{H}_2 \mathrm{O}$$

(b) The complex $$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2$$ is red in colour. Give IUPAC name of its linkage isomer.

Why is boiling point of o-dichlorobenzene higher than p-dichlorobenzene but melting point of para isomer is higher than ortho isomer?