IAT (IISER) 2024 | IAT (IISER) Year Wise Previous Years Questions

IAT (IISER) 2024

MCQ (Single Correct Answer)

-1

Which of the following complexes exhibit(s) magnetic moment close to 2 BM ? $$ \left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]\left(\mathrm{NO}_3\right)_2, \mathrm{~K}_2\left[\mathrm{MnCl}_4\right], \mathrm{K}_4\left[\mathrm{Mn}(\mathrm{CN})_6\right] \text {, and }\left[\mathrm{Ni}(\mathrm{CO})_4\right] $$

$\mathrm{K}_4\left[\mathrm{Mn}(\mathrm{CN})_6\right]$ and $\left[\mathrm{Ni}(\mathrm{CO})_4\right]$

$K_2\left[\mathrm{MnCl}_4\right]$ and $K_4\left[\mathrm{Mn}(\mathrm{CN})_6\right]$

$\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]\left(\mathrm{NO}_3\right)_2$ and $\mathrm{K}_2\left[\mathrm{MnCl}_4\right]$

Only $K_4\left[\mathrm{Mn}(\mathrm{CN})_6\right]$

IAT (IISER) 2024

MCQ (Single Correct Answer)

-1

According to the VSEPR theory, what are the most stable shapes of $X_4 F_4$ and $\mathrm{SF}_4$, respectively?

See-saw and square planar

Both see-saw

Square planar and see-saw

Both square planar

IAT (IISER) 2024

MCQ (Single Correct Answer)

-1

The following complex ions absorb in the ultraviolet-visible region of light. Which one of these shows violet colour?

$$ \left[\mathrm{CoCl}\left(\mathrm{NH}_3\right)_5\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)\left(\mathrm{NH}_3\right)_5\right]^{3+},\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}, \text { and }\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-} $$

$\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)\left(\mathrm{NH}_3\right)_5\right]^{3+}$

$\left[\mathrm{CoCl}\left(\mathrm{NH}_3\right)_5\right]^{2+}$

$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$

$\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-}$

IAT (IISER) 2024

MCQ (Single Correct Answer)

-1

$$ \text { What is the relationship between the structures depicted below? } $$