A solution of $$\mathrm{KCl}(\mathrm{M}=74.5 \mathrm{~g} \mathrm{~mol}^{-1})$$ containing $$1.9 \mathrm{~g}$$ per $$100 \mathrm{~mL}$$ of $$\mathrm{KCl}$$ is isotonic with a solution of urea $$(\mathrm{M}=60.0 \mathrm{~g} \mathrm{~mol}^{-1}$$) containing $$3 \mathrm{~g}$$ per $$100 \mathrm{~mL}$$ of urea. The degree of dissociation of $$\mathrm{KCl}$$ is: [Assume both the solutions are kept at same temperature]
$$\mathrm{Cu}^{+}$$ undergoes disproportionation, according to the equation,
$$ 2 \mathrm{Cu}^{+} \rightleftharpoons \mathrm{Cu}^{2+}+\mathrm{Cu} $$
The $$\mathrm{E}^{\circ}$$ value for the reaction is:
$$[\mathrm{E}_{\mathrm{Cu}^{2+} / \mathrm{Cu}}^{\mathrm{o}}=0.34 \mathrm{~V} \text { and } \mathrm{E}_{\mathrm{Cu}^{2+} / \mathrm{Cu}^{+}}^{\mathrm{O}}=0.15 \mathrm{~V}]$$
Arrange the following amines in the decreasing order of their solubilities in water.
Consider the following reaction
$$(\mathrm{CH}_3)_2 \mathrm{CHCH}_2 \mathrm{Br}+(\mathrm{CH}_3)_3 \mathrm{CCH}_2 \mathrm{Br} \xrightarrow[\Delta]{\mathrm{Na} \text { /dry ether }} \mathrm{X}+\mathrm{Y}+\mathrm{Z}$$
Identify the product which is not formed?