Chemistry
What is the total number of electrons that can have the values $$n=2, l=1, s=1 / 2$$ in the electronic configuration $$1 s^2 2 s^2 2 p^3$$ ?
Calculate the wavelength associated with an electron moving with a velocity of $$10^6 \mathrm{~m} / \mathrm{s}$$ (mass of electron $$=9.1 \times 10^{-31} \mathrm{~kg}, h=6.6 \times 10^{-34} \mathrm{~kg} \mathrm{~m}^2 \mathrm{~s}^{-1}$$ )
Which of the following pairs is not correctly matched?
The orbital diagram in which Aufbau principle is violated is
How does electron affinity change when we move from left to right in a period in the Periodic Table?
Which of the following statements is not correct?
Which of the following statements is correct?
Which of the following oxides of group 16 has the highest boiling point?
Specify the coordination number of cobalt in $$\left[\mathrm{Co}(\mathrm{CN})\left(\mathrm{H}_2 \mathrm{O}\right)(\mathrm{e n})^2\right]^{2+}$$
Which of the following complexes is square planar and diamagnetic?
Which type of isomerism is exhibited by $$\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]$$ ?
When a cation leaves its normal position in the crystal and moves to some interstitial space, the defect in the crystal is known as
In thermodynamics, a quantity whose value simply depends upon the initial and final state of the system is called
If $$\Delta H$$ and $$\Delta S$$ are positive for a reaction, the reaction will be spontaneous only when
A catalyst is a substance which
Consider the reaction,
$$2 \mathrm{~N}_2 \mathrm{O}_5(g) \longrightarrow 4 \mathrm{NO}_2(g)+\mathrm{O}_2(g)$$
The rate law for this reaction is rate $$=k\left[\mathrm{~N}_2 \mathrm{O}_5\right]$$.
Which of the following statements is true regarding the above reaction?
The $$[\mathrm{OH}]^{-}$$ in a solution is $$1 \mathrm{~mol} \mathrm{~L}^{-1}$$. The $$\mathrm{pH}$$ of the solution is
The solubility of $$\mathrm{Fe}(\mathrm{OH})_3$$ is $$x \mathrm{~mol} \mathrm{~L}^{-1}$$. Its $$K_{\mathrm{sp}}$$ would be
When an electrolytic solution conducts electricity, the current is carried by
An electrochemical cell has two half cell reactions as,
$$\begin{aligned} A^{2+}+2 e^{-} & \longrightarrow A ; E_{A^{2+} / A}^0=0.34 \mathrm{~V} \\ X & \longrightarrow X^{2+}+2 e^{-} ; E_{X^{2+} / X}^0=-2.37 \mathrm{~V} \end{aligned}$$
The cell voltage will be
The number of optical isomers of the compound $$\mathrm{CH}_3 \mathrm{CHBrCHBrCOOH}$$ is
Which of the following compounds will exhibit cis-trans (geometrical) isomerism?
The hybridization of carbon atoms in $$\mathrm{C}-\mathrm{C}$$ single bond of $$\mathrm{HC} \equiv \mathrm{C}-\mathrm{CH}=\mathrm{CH}_2$$ is
Which of the following groups is ortho and para directing?
Phenol on treatment with conc. $$\mathrm{HNO}_3$$ gives
Which of the following compounds will be formed when methoxy benzene is reacted with $$\mathrm{HBr}$$ ?
When ethanol and $$\mathrm{I}_2$$ are heated in the presence of $$\mathrm{Na}_2 \mathrm{CO}_3$$, the yellow crystals obtained are of
Identify B in the following series of reaction
$$\mathrm{CH}_3 \mathrm{CHO} \xrightarrow{\mathrm{CH}_3 \mathrm{MgX}} A \xrightarrow{\mathrm{HOH}} B$$
Among the following, the least reactive aldehyde is
Propanal on reaction with lithium aluminium hydride gives
Identify Z in the following sequence
$$\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{I} \xrightarrow{\mathrm{KCN}} X \xrightarrow{\mathrm{H}_3 \mathrm{O}^{+} / \mathrm{H}_2 \mathrm{O}} \mathrm{Y} \xrightarrow[\Delta]{\mathrm{H}_3 \mathrm{O}^{+} / \mathrm{H}_2 \mathrm{O}} Z$$
Treatment of aniline with bromine water produces
Which of the following compounds has maximum acidic character?
$$\mathrm{C}_6 \mathrm{H}_5 \mathrm{COCl} \xrightarrow{\mathrm{NH}_3} X \xrightarrow{\mathrm{P}_2 \mathrm{O}_5} Y \xrightarrow[\mathrm{H}_2]{\mathrm{Ni}} Z$$
the end product in the above sequence of reactions is
Chlorobenzene can be prepared by reacting aniline with
Electrolysis of an aqueous solution of sodium ethanoate gives
The reaction given below is an example of which of the following?
$$2 \mathrm{CH}_3 \mathrm{Br}+2 \mathrm{Na} \xrightarrow{\text { dry ether }} \mathrm{C}_2 \mathrm{H}_6+2 \mathrm{NaBr}$$
Which of the following is least reactive to nitration?
Nucleic acids are polymers of
Which of the following enzymes helps in digestion of proteins?
English
Your friend ............. too much.
We bought ............. books.
Select the antonym for the word 'Bane'.
Pick out the correct synonym of the word 'Treason'.
Mathematics
The value of $$\cos \left(\frac{3 \pi}{2}+x\right) \cos (2 \pi+x)\left\{\cot \left(\frac{3 \pi}{2}-x\right)+\cot (2 \pi+x)\right\}$$ is
If $$\theta=\frac{\pi}{2^n+1}$$, then the value of $$2^n \cos \theta \cos 2 \theta \cos 2^2 \theta \ldots \cos 2^{n-1} \theta$$ is
Using the principal values, the value of $$\sin ^{-1}\left\{\sin \frac{5 \pi}{6}\right\}+\tan ^{-1}\left\{\tan \frac{\pi}{6}\right\}$$ is equal to
Find the value of $$\cos ^{-1}\left(\frac{4}{5}\right)+\tan ^{-1}\left(\frac{3}{5}\right)$$.
If $$A=\left[\begin{array}{ll}3 & -4 \\ 1 & -1\end{array}\right]$$, then $$\left(A-A^{\prime}\right)$$ is equal to (where, $$A^{\prime}$$ is transpose of matrix $$A$$ )
If $$A^{-1}=\left[\begin{array}{rr}5 & -2 \\ -7 & 3\end{array}\right]$$ and $$B^{-1}=\frac{1}{2}\left[\begin{array}{rr}9 & -7 \\ -8 & 6\end{array}\right]$$, then $$(A B)^{-1}$$ is equal to
$$\lim _\limits{x \rightarrow 0}\left\{\tan \left(\frac{\pi}{4}+x\right)\right\}^{1 / x}$$ is equal to
The value of $$\lim _\limits{n \rightarrow \infty}\left\{\frac{1+2+3+\ldots+n}{n+2}-\frac{n}{2}\right\}$$ is
If $$y=1+\frac{x}{1 !}+\frac{x^2}{2 !}+\frac{x^3}{3 !} \ldots$$, then $$\frac{d y}{d x}$$ is equal to
The value of $$\frac{d}{d x}\left(x^n \log _a x e^x\right)$$ is
The interval in which the function $$f(x)=\sin x-\cos x, 0 \leq x \leq 2 \pi$$ is strictly decreasing, is
The slope of normal to the curve $$y=x^3+2 x+6$$ which is parallel to line $$x+14 y+4=0$$ is
If $$f(x)=\left\{\begin{array}{cc}\frac{(1-\cos 4 x)}{x^2}, & \text { if } x < 0 \\ a, & \text { if } x=0, \\ \frac{\sqrt{x}}{\sqrt{(16+\sqrt{x})}-4}, & \text { if } x > 0\end{array}\right.$$ then $$f(x)$$ is continuous at $$x=0$$, for $$a$$
The value of $$\int\limits_0^{\pi / 2} \frac{d x}{1+\tan x}$$ is
Evaluate $$\int \frac{3 x-2}{(x+3)(x+1)^2} d x$$.
The general solution of the linear differential equation $$\frac{d y}{d x}+\sec x \cdot y=\tan x\left(0 \leq x \leq \frac{\pi}{2}\right)$$ is
On solving the differential equation $$x^2 y d x-\left(x^3+y^3\right) d y=0$$, the value of $$\log y$$ is
The particular solution of the differential equation $$\frac{d y}{d x}+y \cot x=2 x+x^2 \cot x$$, such that $$y(\pi / 2)=0$$ is
The area bounded by the circle $$x^2+y^2=16$$ and the line $$y=x$$ in the first quadrant is
The focal distance of the point $$(x, y)$$ from the ellipse $$\frac{x^2}{a^2}+\frac{y^2}{b^2}=1, a>b$$ is
The equation of a straight line which cuts off intercept on $$X$$-axis which is twice that on $$Y$$-axis and is at a unit distance from origin is given by
The equation of a straight line upon which the length of the perpendicular from the origin is 5 and slope of this perpendicular is 3/4 is
The radius of the circle $$(x \cos \theta+y \sin \theta-a)^2+(x \sin \theta-y \cos \theta-b)^2=k^2$$ is
The locus of a point which moves in a plane such that its distance from a fixed point in the plane is always equal to its distance from a fixed straight line in the same plane represents
The eccentricity of the ellipse $$25 x^2+9 y^2-150 x-90 y+225=0$$ is
A bag contains 50 tickets numbered $$1,2,3, ..., 50$$ of which five are drawn at random and arranged in ascending order of magnitude $$\left(x_1 < x_2 < x_3 < x_4< x_5\right)$$, then the probability that $x_3=30$ is
Five persons entered the lift cabin on the ground floor of an eight floor house. Suppose that each of them independently and with equal probability can leave the cabin at any floor beginning with the first, then the probability of all 5 persons leaving at different floors is
If $$(3,4,-1)$$ and $$(-1,2,3)$$ be end points of the diameter of a sphere, then the radius of the sphere is
The following lines are
$$\begin{aligned} \mathbf{r} & =(\hat{\mathbf{i}}+\hat{\mathbf{j}})+\lambda^{\prime}(\hat{\mathbf{i}}+2 \hat{\mathbf{j}}-\hat{\mathbf{k}}), \\ \text { and } \quad \mathbf{r} & =(\hat{\mathbf{i}}+\hat{\mathbf{j}})+\mu(-\hat{\mathbf{i}}+\hat{\mathbf{j}}-2 \hat{\mathbf{k}}) \end{aligned}$$
The position vector of a point $$R$$ which divides the line joining $$P(6,3,-2)$$ and $$Q(3,1,-4)$$ in the ratio $$2 : 1$$ externally is
The angle between the lines $$\frac{x-5}{-3}=\frac{y+3}{-4}=\frac{z-7}{0}, \frac{x}{1}=\frac{y-1}{-2}=\frac{z-6}{2}$$ is
The cartesian product $$A \times A$$ has 9 elements among which are found $$(-1,0)$$ and $$(0,1)$$, then set $$A$$ is equal to
If $$S=\{(a, b): b=|a-1|, a \in Z$$ and $$|a|<3\}$$, where $$Z$$ denotes the set of integers. Then, the range set of $$S$$ is
The quotient of the identity function by the reciprocal function is given by
Which of the following is not a function?
If $$(1+i)(2 i+1)(1+3 i) \ldots(1+n i)=x+i y$$, then $$2 \cdot 5 \cdot 10 \ldots\left(1+n^2\right)$$ is equal to
The non-zero solutions of the equation $$z^2+|z|=0$$, where $$z$$ is a complex number, are
The coefficient of the term independent of $$x$$ in the expansion $$\left(\frac{x+1}{x^{2 / 3}-x^{1 / 3}+1}-\frac{x-1}{x-x^{1 / 2}}\right)^{10}$$ is
Which of the following is the correct principle of Mathematical induction?
The negation of $$\sim s \vee(\sim r \wedge s)$$ is equivalent to
Physics
The Young's modulus of a rope of $$10 \mathrm{~m}$$ length and having diameter of $$2 \mathrm{~cm}$$ is $$200 \times 10^{11} \mathrm{~dyne} / \mathrm{cm}^2$$. If the elongation produced in the rope is $$1 \mathrm{~cm}$$, the force applied on the rope is
The zeroth law of thermodynamics for three systems $$A, B$$ and $$C$$ in contact demands that
The velocity of sound in a gas is $$1300 \mathrm{~m} / \mathrm{s}$$ at STP and specific heat at constant pressure is $$6.84 \mathrm{~cal} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$. The rms velocity at STP is $$(R=1.98 \mathrm{~cal} \mathrm{~K}^{-1} \mathrm{~mol}^{-1})$$
The net electric force on a charge of $$+3 \mu \mathrm{C}$$ at the mid-point on the line joining two charges of magnitude $$+2 \mu \mathrm{C}$$ and $$-2 \mu \mathrm{C}$$ separated by the distance of $$6 \mathrm{~mm}$$, is
A parallel plate capacitor of capacitance $$5 \mu \mathrm{F}$$ is charged to $$120 \mathrm{~V}$$ and then connected to another uncharged capacitor. If the potential falls to $$40 \mathrm{~V}$$, and capacitance of the second capacitor is
24 cells of emf $$1.5 \mathrm{~V}$$ each having internal resistance of $$1 \mathrm{~ohm}$$ are connected to an external resistance of $$1.5 \mathrm{~ohms}$$. To get maximum current
Two straight wires each $$10 \mathrm{~cm}$$ long are parallel to one another and separated by $$2 \mathrm{~cm}$$. When the current flowing in them is $$30 \mathrm{~A}$$ and $$40 \mathrm{~A}$$ respectively, the force experienced by either of the wires is
The alternating current in a circuit is given by $$I=50 \sin 314 t$$. The peak value and frequency of the current are
A bar magnet of pole strength $$10 \mathrm{~Am}$$ is cut into two equal parts breadthwise. The pole strength of each magnet is
A $$50 \mathrm{~Hz}$$ $$\mathrm{AC}$$ signal is applied in a circuit of inductance of $$(1 / \pi) \mathrm{H}$$ and resistance $$2100 \Omega$$. The impedance offered by the circuit is
The magnetic field at a point on the axis of a long solenoid having 5 turns per $$\mathrm{cm}$$ length when a current of $$0.8 \mathrm{~A}$$ flows through it is
An object is $$8 \mathrm{~cm}$$ high. It is desired to form a real image $$4 \mathrm{~cm}$$ high at $$60 \mathrm{~cm}$$ from the mirror. The type of mirror needed with the focal length is
When an object is placed $$40 \mathrm{~cm}$$ from a diverging lens, its virtual image is formed $$20 \mathrm{~cm}$$ from the lens. The focal length and power of lens are
Polonium has a half-life of 140 days. If we take $$20 \mathrm{~g}$$ of polonium initially then the amount of it that remains after 280 days is
According to Bohr model of hydrogen atom, only those orbits are permissible which satisfy the condition
Einstein's photoelectric equation is
The Brewster's law is given by the expression
If two slits in Young's experiment are $$0.4 \mathrm{~mm}$$ apart and fringe width on a screen $$200 \mathrm{~cm}$$ away is $$2 \mathrm{~mm}$$ the wavelength of light illuminating the slits is
The distance of moon form the earth is $$3.8 \times 10^5 \mathrm{~km}$$. Supposing that the eye is most sensitive to the light of wavelength $$550 \mathrm{~nm}$$, the separation of two points on the moon that can be resolved by a $$500 \mathrm{~cm}$$ telescope is
Which of the following logic gates are also known as the Universal gates?
Based on the band theory of conductors, insulators and semi-conductors, the forbidden gap is smallest in
The demodulator or detector circuit consists of a
The power $$(P)$$ of an engine lifting a mass of $$100 \mathrm{~kg}$$ upto a height of $$10 \mathrm{~m}$$ in $$1 \mathrm{~min}$$ is
A silver wire of radius $$0.1 \mathrm{~cm}$$ carries a current of $$2 \mathrm{~A}$$. If the charge density in silver is $$5.86 \times 10^{28} \mathrm{~m}^{-3}$$, the drift velocity is
An electron revolves in a circle at the rate of $$10^{19}$$ rounds per second. The equivalent current is $$\left(e=1.6 \times 10^{-19} \mathrm{C}\right)$$
A hollow sphere of radius $$0.1 \mathrm{~m}$$ has a charge of $$5 \times 10^{-8} \mathrm{C}$$. The potential at a distance of 5 $$\mathrm{cm}$$ from the centre of the sphere is $$\left(\frac{1}{4 \pi \varepsilon_0}=9 \times 10^9 \mathrm{Nm}^2 \mathrm{C}^{-2}\right)$$
The efficiency of a Carnot engine kept at the temperatures of $$27^{\circ} \mathrm{C}$$ and $$127^{\circ} \mathrm{C}$$ is
According to equipartition law of energy each particle in a system of particles have thermal energy $$E$$ equal to
An electric charge does not have which of the following properties?
Two identical capacitors are first connected in series and then in parallel. The ratio of equivalent capacitance is
The horizontal and vertical components of earth's magnetic field at a place are $$0.3 \mathrm{G}$$ and $$0.52 \mathrm{G}$$. The earth's magnetic field and the angle of dip are
A long straight wire is carrying a current of $$12 \mathrm{~A}$$. The magnetic field at a distance of $$8 \mathrm{~cm}$$ is $$\left(\mu_0=4 \pi \times 10^{-7} \mathrm{~N} / \mathrm{A}^2\right)$$
The temperature coefficient of the resistance of a wire is 0.00125 per $${ }^{\circ} \mathrm{C}$$. At $$300 \mathrm{~K}$$ its resistance is $$1 \Omega$$. The resistance of wire will be $$2 \Omega$$ at
Which component of electromagnetic spectrum have maximum wavelength?
The induced emf in a coil of $$10 \mathrm{H}$$ inductance in which current varies from $$9 \mathrm{~A}$$ to $$4 \mathrm{~A}$$ in $$0.2 \mathrm{~s}$$ is
If the alternating current $$I=I_1 \cos \omega t+ I_2 \sin \omega t$$ then the rms current is given by
A conductor of length $$5 \mathrm{~cm}$$ is moved parallel to itself with a speed of $$2 \mathrm{~m} / \mathrm{s}$$, perpendicular to a uniform magnetic field of $$10^{-3} \mathrm{~Wb} / \mathrm{m}^3$$. The induced e.m.f. generated is
The Rutherford scattering experiment proves that an atom consists of
Unpolarised light falls on two polarising sheets placed one on top of other. If the intensity of transmitted light is one fourth of the incident light, the angle between them is
A person has a minimum distance of distinct vision as $$50 \mathrm{~cm}$$. The power of lenses required to read a book at a distance of $$25 \mathrm{~cm}$$ is