1
AIIMS 2019
MCQ (Single Correct Answer)
+1
-0.33

$$\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$$ is a

A
low spin complex
B
paramagnetic
C
high spin
D
$$s p^3 d^2$$-hybridised
2
AIIMS 2019
MCQ (Single Correct Answer)
+1
-0.33

Correct increasing order for the wavelength of absorption in the visible region for the complexes of $$\mathrm{Co}^{3+}$$ is

A
$$\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-},\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+} \text {, } \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{H}_2 \mathrm{O}\right)\right]^{3+},\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right]^{+2}$$
B
$$\begin{aligned} & {\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-},\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{H}_2 \mathrm{O}\right)\right]^{3+}} \\ & {\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right]^{2+},\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}} \end{aligned}$$
C
$$\begin{aligned} & {\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+},\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-},\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{H}_2 \mathrm{O}\right)\right]^{3+},} \\ & {\left[\mathrm{Co}\left(\mathrm{NH}_3\right) \mathrm{Cl}\right]^{+2}} \end{aligned}$$
D
$$\begin{aligned} & {\left[\mathrm{Co}(\mathrm{NH})_5 \mathrm{Cl}\right]^{+2},\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{H}_2 \mathrm{O}\right)\right]^{3+},} \\ & {\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+},\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-}} \end{aligned}$$
3
AIIMS 2019
MCQ (Single Correct Answer)
+1
-0.33

Which of the following complex is optically inactive?

A
$$\left[\mathrm{RhCl}(\mathrm{CO})\left(\mathrm{PPh}_3\right)\left(\mathrm{NH}_3\right)\right]$$
B
$$\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$$
C
$$\left[\mathrm{Fe}(\mathrm{en})_2 \mathrm{Cl}_2\right]$$
D
$$\left[\mathrm{Pd}(\mathrm{en})_2 \mathrm{Cl}_2\right]$$
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