Thermodynamics · Chemistry · BITSAT

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MCQ (Single Correct Answer)

1

The temperature of $$K$$ at which $$\Delta G=0$$, for a given reaction with $$\Delta H=-20.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ and $$\Delta S=-50.0 \mathrm{~JK}^{-1} \mathrm{~mol}^{-1}$$ is

BITSAT 2023
2

A mixture of two moles of carbon monoxide and one mole of oxygen, in a closed vessel is ignited to convert the carbon monoxide to carbon dioxide. If $$\Delta H$$ is the enthalpy change and $$\Delta E$$ is the change in internal energy, then

BITSAT 2023
3

The value of enthalpy change $$(\Delta H)$$ for the reaction $$\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}(l)+3 \mathrm{O}_2(\mathrm{~g}) \longrightarrow 2 \mathrm{CO}_2(\mathrm{~g})+ 3 \mathrm{H}_2 \mathrm{O}(l)$$, at $$27^{\circ} \mathrm{C}$$ is $$-1366 \cdot 5 \mathrm{~kJ} \mathrm{~mol}^{-1}$$. The value of internal energy change for the above reaction at this temperature will be

BITSAT 2023
4

Standard entropy of X2, Y2 and XY3 are 60, 40 and 50 JK$$-$$1mol$$-$$1, respectively. For the reaction, $$\frac{1}{2}$$X2 + $$\frac{3}{2}$$Y2 $$\to$$ XY3, $$\Delta$$H = $$-$$30 kJ, to be at equilibrium, the temperature will be

BITSAT 2022
5

In an adiabatic process, no transfer of heat takes place between system and surrounding. Choose the correct option for free expansion of an ideal gas under adiabatic condition from the following.

BITSAT 2022
6

SI unit of Boltzmann's constant is

BITSAT 2021
7

For the complete combustion of ethanol, $${C_2}{H_5}OH(I) + 3{O_2}(g) \to 2C{O_2}(g) + 3{H_2}O(I)$$, the amount of heat produced as measured in bomb calorimeter is 1364.47 kJ mol$$-$$1 at 25$$^\circ$$C. Assuming ideality the enthalpy of combustion, $$\Delta$$HC, for the reaction will be (R = 8.314 JK$$-$$1 mol$$-$$1)

BITSAT 2021
8

The incorrect expression among the following is

BITSAT 2021
9

Which of the following statement is correct?

BITSAT 2020
10

At the top of a mountain the thermometer reads 0$$^\circ$$C and the barometer reads 710 mm Hg. At the bottom of the mountain the temperature is 30$$^\circ$$C and the pressure is 760 mm Hg. The ratio of the density of air at the top to that of the bottom is

BITSAT 2020
11

The enthalpies of combustion of carbon and carbon monoxide in excess of oxygen at 298 K and constant pressure are $$-$$393.5 kJ/mol and $$-$$280.0 kj/mol respectively. The heat of formation of carbon monoxide at constant volume is

BITSAT 2020
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