Thermodynamics · Chemistry · MHT CET (Biology)

Which from following reactions performs highest + ve work at $25^{\circ} \mathrm{C}$ ?

Calculate standard Gibbs energy for a certain reaction if $\Delta \mathrm{H}^{\circ}$ and $\Delta \mathrm{S}^{\circ}$ respectively are $219 \mathrm{~kJ} \mathrm{~mol}^{-1}$ and $-20 \mathrm{JK}^{-1}$.

Calculate the change in internal energy of the system if 15 kJ of work done on the surrounding and system releases 10 kJ of heat in a particular reaction.

For a certain reaction, $\Delta \mathrm{H}^{\circ}=219 \mathrm{~kJ}$ and $\Delta \mathrm{S}^{\circ}=-21 \mathrm{JK}^{-1}$. Find the value of $\Delta \mathrm{G}^{\circ}$.

Calculate the work done in following reaction.

$$ \begin{aligned} & \mathrm{C}_2 \mathrm{H}_{4(\mathrm{~g})}+\mathrm{HCl}_{(\mathrm{g})} \longrightarrow \mathrm{C}_2 \mathrm{H}_5 \mathrm{Cl}_{(\mathrm{g})} \text { at } 27^{\circ} \mathrm{C} . \\ & \left(\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right) \end{aligned} $$

One mole of a perfect gas expands isothermally and reversibly from $10 \mathrm{dm}^3$ to $20 \mathrm{dm}^3$ at 300 K . Find $\Delta \mathrm{U}, \mathrm{q}$ and work done respectively in the process. $\left(\mathrm{R}=8.3 \times 10^{-3} \mathrm{~kJ} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right)$

Calculate heat of formation of $\mathrm{SO}_2$ from following equations.

$$ \begin{aligned} & \mathrm{S}+\frac{3}{2} \mathrm{O}_2 \longrightarrow \mathrm{SO}_3, \Delta \mathrm{H}=-2 \mathrm{xkJ} \\ & \mathrm{SO}_2+\frac{1}{2} \mathrm{O}_2 \longrightarrow \mathrm{SO}_3, \Delta \mathrm{H}=-\mathrm{ykJ} \end{aligned} $$

Which of the following symbols represents heat of reaction at constant pressure?

The entropy of vaporisation of benzene is $85 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$. When 117 g of benzene vaporises at its boiling point, what is entropy change of surrounding if process is at equilibrium?

Which from following terms is explained by first law of thermodynamics?

What is the change in internal energy for $2 \mathrm{CO}_{(\mathrm{g})}+\mathrm{O}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{CO}_{2(\mathrm{~g})}$ at $25^{\circ} \mathrm{C}$ ?

( $\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}, \Delta \mathrm{H}=-560 \mathrm{~kJ}$ )