1
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Out of Syllabus
Structure of a mixed oxide is cubic close packed (ccp). The cubic unit cell of mixed oxide is composed of oxide ions. One fourth of the tetrahedral voids are occupied by divalent metal A and the octahedral voids are cooupied by a monovalent metal B. The formula of the oxide is
A
ABO2
B
A2BO2
C
A2B3O4
D
AB2O2
2
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Vapour pressure of chloroform (CHCl3) and dichloromethane (CH2Cl2) at 25oC are 200 mm Hg and 41.5 mm Hg respectively. Vapour pressure of the solution obtained by mixing 25.5 g of CHCl3 and 40 g of CH2Cl2 at the same temperature will be
(Molecular mass of CHCl3 = 119.5 u and molecular mass of CH2Cl2 = 85 u)
A
173.9 mm Hg
B
615.0 mm Hg
C
90.6 mm Hg
D
285.5 mm Hg
3
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
Standard reduction potentials of the half reactions are given below :
F2(g) + 2e$$-$$ $$ \to $$ 2F$$-$$(aq) ;   Eo = + 2.85 V
Cl2(g) + 2e$$-$$ $$ \to $$ 2Cl$$-$$(aq) ;   Eo = + 1.36 V
Br2(l) + 2e$$-$$ $$ \to $$ 2Br$$-$$(aq) ;   Eo = + 1.06 V
I2(s) + 2e$$-$$ $$ \to $$ 2I$$-$$(aq) ;  Eo = + 0.53 V

The strongest oxidising and reducing agents 23 respectively are
A
F2 and I$$-$$
B
Br2 and Cl$$-$$
C
Cl2 and Br$$-$$
D
Cl2 and I2
4
AIPMT 2012 Mains
MCQ (Single Correct Answer)
+4
-1
The Gibb's energy for the decomposition of Al2O3 at 500oC is as follows
$${2 \over 3}$$ Al2O3 $$ \to $$ $${4 \over 3}$$ Al + O2
$$\Delta $$rG = +960 kJ mol$$-$$1
The potential difference needed for the electrolytic reduction of aluminium oxide (Al2O3) at 500oC is at least
A
4.5 V
B
3.0 V
C
2.5 V
D
5.0 V
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