The ratio of sigma and $$\pi$$ bonds present in pyrophosphoric acid is ___________.

The number of species from the following carrying a single lone pair on central atom Xenon is ___________.

$$\mathrm{XeF}_{5}^{+}, \mathrm{XeO}_{3}, \mathrm{XeO}_{2} \mathrm{~F}_{2}, \mathrm{XeF}_{5}^{-}, \mathrm{XeO}_{3} \mathrm{~F}_{2}, \mathrm{XeOF}_{4}, \mathrm{XeF}_{4}$$

The observed magnetic moment of the complex $$\left.\left[\operatorname{Mn}(\underline{N} C S)_{6}\right)\right]^{x^{-}}$$ is $$6.06 ~\mathrm{BM}$$. The numerical value of $$x$$ is __________.

Coagulating value of the electrolytes $$\mathrm{AlCl}_{3}$$ and $$\mathrm{NaCl}$$ for $$\mathrm{As}_{2} \mathrm{S}_{3}$$ are 0.09 and 50.04 respectively. The coagulating power of $$\mathrm{AlCl}_{3}$$ is $$x$$ times the coagulating power of $$\mathrm{NaCl}$$. The value of $$\underline{x}$$ is ___________.