The possibility of photochemical smog formation will be minimum at :

Decreasing order of reactivity towards electrophilic substitution for the following compounds is :

For a reversible reaction $\mathrm{A} \rightleftharpoons \mathrm{B}$, the $\Delta \mathrm{H}_{\text{forward reaction}} = 20 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The activation energy of the uncatalysed forward reaction is $300 \mathrm{~kJ} \mathrm{~mol}^{-1}$. When the reaction is catalysed keeping the reactant concentration same, the rate of the catalysed forward reaction at $27^{\circ} \mathrm{C}$ is found to be same as that of the uncatalysed reaction at $327^{\circ} \mathrm{C}$.

The activation energy of the catalysed backward reaction is ___________ $\mathrm{kJ}~ \mathrm{mol}^{-1}$.

The volume (in $\mathrm{mL}$) of $0.1 \mathrm{M} ~\mathrm{AgNO}_{3}$ required for complete precipitation of chloride ions present in $20 \mathrm{~mL}$ of $0.01 \mathrm{M}$ solution of $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{2}$ as silver chloride is __________.