Given below are two reactions, involved in the commercial production of dihydrogen (H$$_2$$). The two reactions are carried out at temperature "T$$_1$$" and "T$$_2$$", respectively

$$C(s) + {H_2}O(g)\buildrel {{T_1}} \over \longrightarrow CO(g) + {H_2}(g)$$

$$CO(g) + {H_2}O(g)\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{Catalyst}^{{T_2}}} C{O_2}(g) + {H_2}(g)$$

The temperatures T$$_1$$ and T$$_2$$ are correctly related as :

Given

$$\mathrm{\Delta H^0}$$ for the reaction

$$\mathrm{C(graphite)+\frac{1}{2}O_2(g)\to CO(g)}$$ is :

Match List I with List II

Choose the correct answer from the options given below :

Isomeric amines with molecular formula C$$_8$$H$$_{11}$$N give the following tests

Isomer (P) $$\Rightarrow$$ Can be prepared by Gabriel phthalimide synthesis

Isomer (Q) $$\Rightarrow$$ Reacts with Hinsberg's reagent to give solid insoluble in NaOH

Isomer (R) $$\Rightarrow$$ Reacts with HONO followed by $$\beta$$-naphthol in NaOH to give red dye.

Isomers (P), (Q) and (R) respectively are