A 42.12% (w/v) solution of NaCl causes precipitation of a certain sol in 10 hours. The coagulating value of NaCl for the sol in 2 hours is :

[Given : Molar mass : Na = 23.0 g mol^$$-$$1 ; Cl = 35.5 g mol^$$-$$1]

Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : The first ionization enthalpy for oxygen is lower than that of nitrogen.

Reason R : The four electrons in 2p orbitals of oxygen experience more electron-electron repulsion.

In the light of the above statements, choose the correct answer from the options given below.

Match List I with List II.

Choose the correct answer from the options given below :

Given below are two statements.

$$\bullet$$ Statement I : In CuSO₄ . 5H₂O, Cu-O bonds are present.

$$\bullet$$ Statement II : In CuSO₄ . 5H₂O, ligands coordinating with Cu(II) ion are O-and S-based ligands.

In the light of the above statements, choose the correct answer from the options given below.