Match the following items in column I with the corresponding items in column II.

Item I		Item II
(i)	Na2CO3.10H2O	(A)	Portland cement ingredient
(ii)	Mg(HCO3)2	(B)	Castner-Kellner process
(iii)	NaOH	(C)	Solvay process
(iv)	Ca3Al2O6	(D)	Temporary hardness

25 ml of the given HCl solution requires 30 mL of 0.1 M sodium carbonate solution. What is the volume of this HCl solution required to titrate 30 mL of 0.2 M aqueous NaOH solutions ?

The reaction that does NOT define calcination is :

$$\underline A \,\,\buildrel {4KOH,{O_2}} \over \longrightarrow \,\,\mathop {2\underline B }\limits_{\left( {Green} \right)} \,\, + \,\,2{H_2}O$$

$$3\underline B \,\,\buildrel {4HCl} \over \longrightarrow \,\,\mathop {2\underline C }\limits_{\left( {Purple} \right)} \,\, + \,\,Mn{O_2} + 2{H_2}O$$

$$2\underline C \,\,\buildrel {{H_2}O.KI} \over \longrightarrow \,\,\mathop {2\underline A }\limits_{\left( {Purple} \right)} \,\, + \,\,2KOH\,\, + \,\,\underline D $$

In the above sequence of reactions, $${\underline A }$$ and $${\underline D }$$, respectively, are :