Adsorption of a gas on a surface follows Freundlich adsorption isotherm. Plot of log $${x \over m}$$ versus log p gives a straight line with slope equal to 0.5, then:

( $${x \over m}$$ is the mass of the gas adsorbed per gram of adsorbent)

A solution is prepared by mixing 8.5 g of CH₂Cl₂ and 11.95 g of CHCl₃ . If vapour pressure of CH₂Cl₂ and CHCl₃ at 298 K are 415 and 200 mmHg respectively, the mole fraction of CHCl₃ in vapour form is : (Molar mass of Cl = 35.5 g mol⁻¹)

The rate of a reaction quadruples when the temperature changes from 300 to 310 K. The activation energy of this reaction is :

(Assume activation energy and preexponential factor are independent of temperature; ln 2 = 0.693; R = 8.314 J mol⁻¹ K⁻¹)

The electronic configuration with the highest ionization enthalpy is :