JEE Main
Chemistry
Equilibrium
Previous Years Questions

The effect of addition of helium gas to the following reaction in equilibrium state, is : $$\mathrm{PCl}_{5}(\mathrm{g}) \rightleftharpoons \mathrm{PC... Henry’s constant (in kbar) for four gases$$\alpha $$,$$\beta $$,$$\gamma $$and$$\delta $$in water at 298 K is given below : .tg {border-collap... ## Numerical (i)$$\mathrm{X}(\mathrm{g}) \rightleftharpoons \mathrm{Y}(\mathrm{g})+\mathrm{Z}(\mathrm{g}) \quad \mathrm{K}_{\mathrm{p} 1}=3$$(ii)$$\mathrm{A}(\m...
At $298 \mathrm{~K}$, the solubility of silver chloride in water is $1.434 \times 10^{-3} \mathrm{~g} \mathrm{~L}^{-1}$. The value of $-\log \mathrm{K... For reaction : $$\mathrm{SO}_{2}(\mathrm{~g})+\frac{1}{2} \mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons \mathrm{SO}_{3}(\mathrm{~g})$$ $$\mathrm{K}_{... Consider the following equation: 2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g), \Delta H=-190 \mathrm{~kJ} The n...$$600 \mathrm{~mL}$$of$$0.01~\mathrm{M} ~\mathrm{HCl}$$is mixed with$$400 \mathrm{~mL}$$of$$0.01~\mathrm{M} ~\mathrm{H}_{2} \mathrm{SO}_{4}$$. T... At 298 K$$\mathrm{N_2~(g)+3H_2~(g)\rightleftharpoons~2NH_3~(g),~K_1=4\times10^5}\mathrm{N_2~(g)+O_2~(g)\rightleftharpoons~2NO~(g),~K_2=1.6\times... Millimoles of calcium hydroxide required to produce 100 mL of the aqueous solution of pH 12 is $$x\times10^{-1}$$. The value of $$x$$ is ___________ (... Solid Lead nitrate is dissolved in 1 litre of water. The solution was found to boil at 100.15$$^\circ$$C. When 0.2 mol of NaCl is added to the resulti... Water decomposes at 2300 K $$\mathrm{H_2O(g)\to H_2(g)+\frac{1}{2}O_2(g)}$$ The percent of water decomposing at 2300 K and 1 bar is ___________ (Neare... Consider the following reaction approaching equilibrium at 27$$^\circ$$C and 1 atm pressure $$\mathrm{A+B}$$ $$\mathrel{\mathop{\kern0pt\rightleftharp... A litre of buffer solution contains 0.1 mole of each of NH$$_3$$and NH$$_4$$Cl. On the addition of 0.02 mole of HCl by dissolving gaseous HCl, the pH... The dissociation constant of acetic acid is$$x\times10^{-5}$$. When 25 mL of 0.2$$\mathrm{M~CH_3COONa}$$solution is mixed with 25 mL of 0.02$$\mat... If the solubility product of PbS is 8 $$\times$$ 10$$-$$28, then the solubility of PbS in pure water at 298 K is x $$\times$$ 10$$-$$16 mol L$$-$$1. T... At $$600 \mathrm{~K}, 2 \mathrm{~mol}$$ of $$\mathrm{NO}$$ are mixed with $$1 \mathrm{~mol}$$ of $$\mathrm{O}_{2}$$. $$2 \mathrm{NO}_{(\mathrm{g})}+\m... At$$310 \mathrm{~K}$$, the solubility of$$\mathrm{CaF}_{2}$$in water is$$2.34 \times 10^{-3} \mathrm{~g} / 100 \mathrm{~mL}$$. The solubility prod... In the titration of$$\mathrm{KMnO}_{4}$$and oxalic acid in acidic medium, the change in oxidation number of carbon at the end point is ___________.... At$$298 \mathrm{~K}$$, the equilibrium constant is$$2 \times 10^{15}$$for the reaction :$$\mathrm{Cu}(\mathrm{s})+2 \mathrm{Ag}^{+}(\mathrm{aq}) \... 2NOCl(g) $$\rightleftharpoons$$ 2NO(g) + Cl2(g) In an experiment, 2.0 moles of NOCl was placed in a one-litre flask and the concentration of NO after ... 40% of HI undergoes decomposition to H2 and I2 at 300 K. $$\Delta$$G$$^\Theta$$ for this decomposition reaction at one atmosphere pressure is _______... 50 mL of 0.1 M CH3COOH is being titrated against 0.1 M NaOH. When 25 mL of NaOH has been added, the pH of the solution will be _____________ $$\times... PCl5 dissociates as PCl5(g)$$\rightleftharpoons$$PCl3(g) + Cl2(g) 5 moles of PCl5 are placed in a 200 litre vessel which contains 2 moles of N2 and ... 2O3(g)$$\rightleftharpoons$$3O2(g) At 300 K, ozone is fifty percent dissociated. The standard free energy change at this temperature and 1 atm press... The molar solubility of Zn(OH)2 in 0.1 M NaOH solution is x$$\times$$10$$-$$18 M. The value of x is _________ (Nearest integer)(Given : The solubili... 1.22 g of an organic acid is separately dissolved in 100 g of benzene (Kb = 2.6 K kg mol$$-$$1) and 100 g of acetone (Kb = 1.7 K kg mol$$-$$1). The ac... The pH of a solution obtained by mixing 50 mL of 1 M HCl and 30 mL of 1 M NaOH is x$$\times$$10$$-$$4. The value of x is ____________. (Nearest inte... A3B2 is a sparingly soluble salt of molar mass M (g mol$$-$$1) and solubility x g L$$-$$1. The solubility product satisfies$${K_{sp}} = a{\left( {{x ... When 5.1 g of solid NH4HS is introduced into a two litre evacuated flask at 27$$^\circ$$C, 20% of the solid decomposes into gaseous ammonia and hydrog... The number of moles of NH3, that must be added to 2L of 0.80 M AgNO3 in order to reduce the concentration of Ag+ ions to 5.0 $$\times$$ 10$$-$$8 M (Kf... The equilibrium constant Kc at 298 K for the reaction A + B $$\rightleftharpoons$$ C + D is 100. Starting with an equimolar solution with concentratio... The OH$$-$$ concentration in a mixture of 5.0 mL of 0.0504 M NH4Cl and 2 mL of 0.0210 M NH3 solution is x $$\times$$ 10$$-$$6 M. The value of x is ___... The equilibrium constant for the reactionA(s) $$\rightleftharpoons$$ M(s) + $${1 \over 2}$$O2(g)is Kp = 4. At equilibrium, the partial pressure of O2 ... 2SO2(g) + O2(g) $$\to$$ 2SO3(g)The above reaction is carried out in a vessel starting with partial pressure PSO2 = 250 m bar, PO2 = 750 m bar and PSO3... PCl5 $$\rightleftharpoons$$ PCl3 + Cl3Kc = 1.8443.0 moles of PCl5 is introduced in a 1 L closed reaction vessel at 380 K. The number of moles of PCl5 ... Assuming that Ba(OH)2 is completely ionised in aqueous solution under the given conditions the concentration of H3O+ ions in 0.005 M aqueous solution ... CO2 gas is bubbled through water during a soft drink manufacturing process at 298 K. If CO2 exerts a partial pressure of 0.835 bar then x m mol of CO2... For the reactionA + B $$\rightleftharpoons$$ 2Cthe value of equilibrium constant is 100 at 298 K. If the initial concentration of all the three specie... Value of KP for the equilibrium reactionN2O4(g) $$\rightleftharpoons$$ 2NO2(g) at 288 K is 47.9. The KC for this reaction at same temperature is _____... 2SO2(g) + O2(g) $$\rightleftharpoons$$ 2SO3(g)In an equilibrium mixture, the partial pressures are PSO3 = 43 kPa; PO2 = 530 Pa and PSO2 = 45 kPa. The ... The gas phase reaction $$2A(g) \rightleftharpoons {A_2}(g)$$ at 400 K has $$\Delta$$Go = + 25.2 kJ mol-1.The equilibrium constant KC for this reaction... The solubility of CdSO4 in water is 8.0 $$\times$$ 10$$-$$4 mol L$$-$$1. Its solubility in 0.01 M H2SO4 solution is __________ $$\times$$ 10$$-$$6 mol... In order to prepare a buffer solution of pH 5.74, sodium acetate is added to acetic acid. If the concentration of acetic acid in the buffer is 1.0 M, ... 2 molal solution of a weak acid HA has a freezing point of 3.885$$^\circ$$C. The degree of dissociation of this acid is ___________ $$\times$$ 10$$-$$... A 1 molal K4Fe(CN)6 solution has a degree of dissociation of 0.4. Its boiling point is equal to that of another solution which contains 18.1 weight pe... 0.01 moles of a weak acid HA (Ka = 2.0 $$\times$$ 10$$-$$6) is dissolved in 1.0 L of 0.1 M HCl solution. The degree of dissociation of HA is _________... The oxygen dissolved in water exerts a partial pressure of 20 kPa in the vapour above water. The molar solubility of oxygen in water is __________ $$\... Sulphurous acid (H2SO3) has Ka1 = 1.7$$\times$$10$$-$$2 and Ka2 = 6.4$$\times$$10$$-$$8. The pH of 0.588 M H2SO3 is __________. (Round off to the ... Two salts A2X and MX have the same value of solubility product of 4.0$$\times$$10$$-$$12. The ratio of their molar solubilities i.e.$${{S({A_2}X)} ... For the reaction $$A(g) \rightleftharpoons B(g)$$ at 495 K, $$\Delta$$rG$$^\circ$$ = $$-$$9.478 kJ mol$$-$$1.If we start the reaction in a closed cont... When 12.2 g of benzoic acid is dissolved in 100 g of water, the freezing point of solution was found to be $$-$$0.93$$^\circ$$C (Kf(H2O) = 1.86 K kg m... The pH of ammonium phosphate solution, if pka of phosphoric acid and pkb of ammonium hydroxide are 5.23 and 4.75 respectively, is ___________.... A homogeneous ideal gaseous reaction $$A{B_{2(g)}} \rightleftharpoons {A_{(g)}} + 2{B_{(g)}}$$ is carried out in a 25 litre flask at 27$$^\circ$$C. Th... The solubility product of PbI2 is 8.0 $$\times$$ 10$$-$$9. The solubility of lead iodide in 0.1 molar solution of lead nitrate is x $$\times$$ 10$$-$$... Assuming ideal behaviour, the magnitude of log K for the following reaction at 25$$^\circ$$C is x $$\times$$ 10$$-$$1. The value of x is _________. (I... The stepwise formation of $${\left[ {Cu{{\left( {N{H_3}} \right)}_4}} \right]^{2 + }}$$ is given below: The value of stability constants K1, K2, K3 a... At 1990 K and 1 atm pressure, there are equal number of Cl2, molecules and Cl atoms in the reaction mixture. The value of Kp for the reaction Cl2 (g) ... For the reaction A(g) $$\to$$ B(g) the value of the equilibrium constant at 300 K and 1 atm is equal to 100.0. The value of $$\Delta$$rG for the re... For a reaction X + Y ⇌ 2Z , 1.0 mol of X, 1.5 mol of Y and 0.5 mol of Z were taken in a 1 L vessel and allowed to react. At equilibrium, the concentra... For the disproportionation reaction 2Cu+(aq) ⇌ Cu(s) + Cu2+(aq) at 298 K. ln K (where K is the equilibrium constant) is ___________ × 10–1. Given : ($...
10.30 mg of O2 is dissolved into a liter of sea water of density 1.03 g/mL. The concentration of O2 in ppm is__________.
3 g of acetic acid is added to 250 mL of 0.1 M HCL and the solution made up to 500 mL. To 20 mL of this solutions $${1 \over 2}$$ mL of 5 M NaOH is ad...
Two solutions, A and B, each of 100L was made by dissolving 4g of NaOH and 9.8 g of H2SO4 in water, respectively. The pH of the resultant solution obt...

## MCQ (Single Correct Answer)

The incorrect statement for the use of indicators in acid-base titration is :
When $$\mathrm{Cu}^{2+}$$ ion is treated with $$\mathrm{KI}$$, a white precipitate, $$\mathrm{X}$$ appears in solution. The solution is titrated with ...
When the hydrogen ion concentration [H$$^+$$] changes by a factor of 1000, the value of pH of the solution __________
Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.
$$200 \mathrm{~mL}$$ of $$0.01 \,\mathrm{M} \,\mathrm{HCl}$$ is mixed with $$400 \mathrm{~mL}$$ of $$0.01 \,\mathrm{M} \,\mathrm{H}_{2} \mathrm{SO}_{4... A compound 'X' is a weak acid and it exhibits colour change at pH close to the equivalence point during neutralization of NaOH with$$\mathrm{CH}_{3} ...
Given below are two statements : One is labelled as Assertion A and the other is labelled as Reason R Assertion A : Permanganate titrations are not pe...
The plot of $$\mathrm{pH}$$-metric titration of weak base $$\mathrm{NH}_{4} \mathrm{OH}$$ vs strong acid HCl looks like :
Class XII students were asked to prepare one litre of buffer solution of $$\mathrm{pH} \,8.26$$ by their Chemistry teacher: The amount of ammonium chl...
$$20 \mathrm{~mL}$$ of $$0.1\, \mathrm{M} \,\mathrm{NH}_{4} \mathrm{OH}$$ is mixed with $$40 \mathrm{~mL}$$ of $$0.05 \mathrm{M} \mathrm{HCl}$$. The $... $$\Delta$$G$$^\circ$$ vs T plot for the formation of MgO, involving reaction 2Mg + O2 $$\to$$ 2MgO, will look like : 4.0 moles of argon and 5.0 moles of PCl5 are introduced into an evacuated flask of 100 litre capacity at 610 K. The system is allowed to equilibrate. ... A student needs to prepare a buffer solution of propanoic acid and its sodium salt with pH 4. The ratio of $${{[C{H_3}C{H_2}CO{O^ - }]} \over {[C{H_3}... The Ksp for bismuth sulphide (Bi2S3) is 1.08$$\times$$10$$-$$73. The solubility of Bi2S3 in mol L$$-$$1 at 298 K is... Given below are two statements one is labelled as Assertion A and the other is labelled as Reason R : Assertion A : The amphoteric nature of water is ... For a reaction at equilibrium A(g)$$\rightleftharpoons$$B(g) +$${1 \over 2}$$C(g) the relation between dissociation constant (K), degree of dissoc... Given below are two statements.Statement I : In the titration between strong acid and weak base methyl orange is suitable as an indicator.Statement II... A solution is 0.1 M in Cl$$-$$and 0.001 M in CrO$$_4^{2 - }$$. Solid AgNO3 is gradually added to it. Assuming that the addition does not change in vo... Which of the following compound CANNOT act as a Lewis base? The solubility of Ca(OH)2 in water is :[Given : The solubility product of Ca(OH)2 in water = 5.5$$\times$$10$$-$$6]... The solubility of AgCN in a buffer solution of pH = 3 is x. The value of x is : [Assume : No cyano complex is formed; Ksp(AgCN) = 2.2$$\times$$10$$-... For the reaction Fe2N(s) + $${3 \over 2}$$H2(g) ⇌ 2Fe(s) + NH3(g) Arrange the following solutions in the decreasing order of pOH : (A) 0.01 M HCl (B) 0.01 M NaOH (C) 0.01 M CH3COONa (D) 0.01 M NaCl ... The variation of equilibrium constant with temperature is given below : .tg {border-collapse:collapse;border-spacing:0;} .tg td{border-color:black;b... Consider the following reaction: N2O4(g) ⇌ 2NO2(g); $$\Delta$$Ho = +58 kJ For each of the following cases (a, b), the direction in which the equilibr... If the equilibrium constant for A ⇌ B + C is $$K_{eq}^{(1)}$$ and that of B + C ⇌ P is $$K_{eq}^{(2)}$$, the equilibrium constant for A ⇌ P is :... For the equilibrium A ⇌ B , the variation of the rate of the forward (a) and reverse (b) reaction with time is given by 100 mL of 0.1 M HCl is taken in a beaker and to it 100 mL of 0.1 M NaOH is added in steps of 2 mL and the pH is continuously measured. Which of the fo... An acidic buffer is obtained on mixing : For the following Assertion and Reason, the correct option is Assertion (A): When Cu (II) and sulphide ions are mixed, they react together extremely q... An open beaker of water in equilibrium with water vapour is in a sealed container. When a few grams of glucose are added to the beaker of water, the r... While titrating dilute HCl solution with aqueous NaOH, which of the following will not be required? In the figure shown below reactant A (represented by square) is in equilibrium with product B (represented by circle). The equilibrium constant is : ... The solubility product of Cr(OH)3 at 298 K is 6.0 × 10–31. The concentration of hydroxide ions in a saturated solution of Cr(OH)3 will be :... The Ksp for the following dissociation is 1.6 × 10–5 $$PbC{l_{2(s)}} \leftrightharpoons Pb_{(aq)}^{2 + } + 2Cl_{(aq)}^ -$$ Which of the following cho... For the following Assertion and Reason, the correct option is : Assertion : The pH of water increases with increase in temperature. Reason : The disso... The stoichiometry and solubility product of a salt with the solubility curve given below is, respectively : ... Oxidation number of potassium in K2O. K2O2 and KO2 respectively is : In which one of the following equilibria, Kp $$\ne$$ KC ? The molar solubility of Cd(OH)2 is 1.84 × 10–5 M in water. The expected solubility of Cd(OH)2 in a buffer solution of pH = 12 is : ... What is the molar solubility of Al(OH)3 in 0.2 M NaOH solution ? Given that, solubility product of Al(OH)3 = 2.4 × 10–24 :... For the reaction, 2SO2(g) + O2(g) = 2SO3(g), $$\Delta$$H = –57.2 kJ mol–1 and KC = 1.7 × 1016 Which of the following statement is incorrect ? ... The pH of a 0.02 M NH4Cl solution will be [given Kb (NH4OH) = 10–5 and log 2 = 0.301] Consider the following statements (a) The pH of a mixture containing 400 mL of 0.1 M H2SO4 and 400 mL of 0.1 M NaOH will be approximately 1.3 (b) Ioni... For the following reactions, equilibrium constants are given : S(s) + O2(g) ⇋ SO2(g); K1 = 1052 2S(s) + 3O2(g) ⇋ 2SO3(g); K2 = 10129 The equilibriu... In a chemical reaction, the initial concentration of B was 1.5 times of the concentration of A, but the equilibrium concentrations of A and B were f... Two solids dissociate as follows – The total pressure when both the solids dissociated simultaneously is - ... For the equilibrium, 2H2O $$\rightleftharpoons$$ H3O+ + OH$$-$$, the value of $$\Delta$$Go at 298 K is approximately : ... Given the equilibrium constant: KC of the reaction : Cu(s) + 2Ag+ (aq) $$\to$$ Cu2+ (aq) + 2Ag(s) is 10 $$\times$$ 1015, calculate the E$$_{cel... Consider the reaction N2(g) + 3H2(g)$$\rightleftharpoons$$2NH3(g) The equilibrium constant of the above reaction is Kp. If pure ammonia is lef... 5.1 g NH4SH is introduced in 3.0 L evacuated flask at 327ºC. 30% of the solid NH4SH decomposed to NH3 and H2S as gases . The Kp of the reaction at 327... The pH of rain water, is approximately : If the standard electrode potential for a cell is 2 V at 300 K, the equilibrium constant (K) for the reaction Zn(s) + Cu2+ (aq)$$\rightleftharpoons$...
20 mL of 0.1 M H2SO4 solution is added to 30 mL of of 0.2 M NH4OH solution. The pH of the resultant mixture is : [pkb of NH4OH = 4.7]....
The gas phase reaction 2NO2(g) $$\to$$ N2O4(g) is an exothermic reaction. The decomposition of N2O4, in equilibrium mixture of NO2(g) and N2O4(g),...
An aqueous solution contains an unknown concentration of Ba2+. When 50 mL of a 1 M solution of Na2SO4 is added, BaSO4 just begins to precipitate. The ...
An aqueous solution contains 0.10 M H2S and 0.20 M HCl. If the equilibrium constants for the formation of HS– from H2S is 1.0 $$\times$$ 10–7 and that...
Which of the following are Lewis acids?
Which of the following salts is the most basic in aqueous solution?
Following four solutions are prepared by mixing different volumes of NaOH and HCl of different concentrations, pH of which one of them will be equal t...
At a certain temperature in a $$5$$ $$L$$ vessel, 2 moles of carbon monoxide and 3 moles of chlorine were allowed to reach equilibrium according to th...
The minimum volume of water required to dissolve 0.1 g lead (II) chloride to get a saturated solution (Ksp of PbCl2 = 3.2 $$\times$$ 10-8 atomic ma...
In which of the following reactions, an increase in the volume of the container will favour the formation of products?
Which of the following is a Lewis acid ?
50 mL of 0.2 M ammonia solution is treated with 25 mL of 0.2 M HCl. If pKb of ammonia solution is 4.75, the pH of the mixture will be :
Additin of sodium hydroxide solution to a weak acid (HA)results in a buffer of pH 6. If ionition constant of HA is 10$$-$$5, the ratio of salt to acid...
pKa of a weak acid (HA) and pKb of a weak base (BOH) are 3.2 and 3.4, respectively. The pH of their salt (AB) solution is:
A solid XY kept in an evacuated sealed container undergoes decomposition to form a mixture of gases X and Y at temperature T. The equilibrium pressure...
For the reaction, A(g) + B(g) $$\to$$ C(g) + D(g), $$\Delta$$Ho and $$\Delta$$So are, respectively, − 29.8 kJ mol−1 and −0.100 kJ K−1 mol−1 at 2...
The plot shows the variation of −$$ln$$ Kp versus temperature for the two reactions. M(s) + $${1 \over 2}$$ O2(g) $$\to$$ MO(s) and C(s) + $${1 \ov... The equilibrium constant at 298 K for a reaction A + B$$\leftrightharpoons$$C + D is 100. If the initial concentration of all the four species were ... The standard Gibbs energy change at 300 K for the reaction 2A$$\leftrightharpoons$$B + C is 2494.2 J. At a given time, the composition of the reacti... The following reaction is performed at 298 K 2NO(g) + O2 (g)$$\leftrightharpoons$$2NO2 (g) The standard free energy of formation of NO(g) is 86.6 ... For the reaction SO2 (g) +$${1 \over 2} O_2(g) \leftrightharpoons$$SO3(g). if KP = KC(RT)x where the symbols have usual meaning then the value of ... How many litres of water must be added to 1 litre of an aqueous solution of HCl with a pH of 1 to create an aqueous solution with pH of 2? The pH of a 0.1 molar solution of the acid HQ is 3. The value of the ionization constant, Ka of this acid is : The equilibrium constant (KC) for the reaction N2(g) + O2(g)$$\to$$2NO(g) at temperature T is 4$$\times$$10–4. The value of KC for the reaction, N... A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted into CO on the addition of graphite. If the total pressure at... Three reactions involving$$H_2PO_4^−$$are given below : (i) H3PO4 + H2O$$\to$$H3O+ +$$H_2PO_4^−$$(ii)$$H_2PO_4^−$$+ H2O$$\toHPO_4^{2−}$$... At 25°C, the solubility product of Mg(OH)2 is 1.0$$\times$$10–11. At which pH, will Mg2+ ions start precipitating in the form of Mg(OH)2 from a solu... In aqueous solution the ionization constants for carbonic acid are K1 = 4.2 x 10–7 and K2 = 4.8 x 10–11 Select the correct statement for a saturated 0... Solubility product of silver bromide is 5.0$$\times$$10–13. The quantity of potassium bromide (molar mass taken as 120g of mol–1) to be added to 1 l... Solid Ba(NO3)2 is gradually dissolved in a 1.0$$\times$$10-4 M Na2CO3 solution. At what concentration of Ba2+ will a precipitate begin to form ? (Ks... The equilibrium constants KP1 and KP2 for the reactions X$$\leftrightharpoons$$2Y and Z$$\leftrightharpoons$$P + Q, respectively are in the ratio... Four species are listed below i.$$HCO_3^−$$ii.$$H_3O^+$$iii.$$HSO_4^−$$iv.$$HSO_3F$$Which one of the following is the correct sequence of th... The pKa of a weak acid, HA, is 4.80. The pKb of a weak base, BOH, is 4.78. The pH of an aqueous solution of the corresponding salt, BA, will be... For the following three reactions a, b and c, equilibrium constants are given: a. CO (g) + H2O (g)$$\leftrightharpoons$$CO2(g) + H2 (g) ; K1 b. CH4... The first and second dissociation constants of an acid H2A are 1.0$$\times$$10−5 and 5.0$$\times$$10−10 respectively. The overall dissociation co... In a sautrated solution of the sparingly soluble strong electrolyte AgIO3 (Molecular mass = 283) the equilibrium which sets in is AgIO3(s)$$\leftrig...
The pKa of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA in which 50% of the acid is ionized is
Phosphorus pentachloride dissociates as follows, in a closed reaction vessel PCl5 (g) $$\leftrightharpoons$$ PCl3 (g) + Cl2 (g) If total pressure at ...
The equilibrium constant for the reaction SO3 (g) $$\leftrightharpoons$$ SO2 (g) + $$1 \over 2$$ O2 (g) is Kc = 4.9 $$\times$$ 10–2. The value of Kc...
Given the data at 25oC, Ag + I- $$\to$$ AgI + e- , Eo = 0.152 V Ag $$\to$$ Ag+ + e-, Eo = -0.800 V What is the value of log Ksp for AgI? (2.303 RT/F ...
If $$\alpha$$ is the degree of dissociation of Na2SO4, the vant Hoff’s factor (i) used for calculating the molecular mass is
The solubility product of a salt having general formula MX2, in water is: 4 $$\times$$ 10-12 . The concentration of M2+ ions in the aqueous solution o...
The exothermic formation of ClF3 is represented by the equation: Cl2 (g) + 3F2 (g) $$\leftrightharpoons$$ 2ClF3 (g); $$\Delta H$$ = -329 kJ Which of ...
For the reaction 2NO2 (g) $$\leftrightharpoons$$ 2NO (g) + O2 (g), (Kc = 1.8 $$\times$$ 10-6 at 184oC) (R = 0.0831 kJ/(mol. K)) When Kp and Kc are com...
What is the conjugate base of OH-?
Hydrogen ion concentration in mol / L in a solution of pH = 5.4 will be
An amount of solid NH4HS is placed in a flask already containing ammonia gas at a certain temperature and 0.50 atm. Pressure. Ammonium hydrogen sulphi...
The conjugate base of H2PO4- is
What is the equilibrium expression for the reaction P4 (s) + 5O2 $$\leftrightharpoons$$ P4O10 (s)?
For the reaction, CO(g) + Cl2(g) $$\leftrightharpoons$$ COCl2(g) the $${{{K_p}} \over {{K_c}}}$$ is equal to
The equilibrium constant for the reaction N2(g) + O2(g) $$\leftrightharpoons$$ 2NO(g) at temperature T is 4 $$\times$$ 10-4. The value of Kc for the r...
The molar solubility (in ol L-1) of a sparingly soluble salt MX4 is "s". The corresponding solubility product is Ksp. 's' is given in term of Ksp by t...
The solubility in water of a sparingly soluble salt AB2 is 1.0 $$\times$$ 10-5 mol L-1. Its solubility product number will be...
Which one of the following statements is not true?
Consider the reaction equilibrium 2 SO2 (g) + O2 (g) $$\leftrightharpoons$$ 2 SO3 (g); $$\Delta H^o$$ = -198 kJ One the basis of Le Chatelier's princi...
For the reaction equilibrium N2O4 (g) $$\leftrightharpoons$$ 2NO2 (g) the concentrations of N2O4 and NO2 at equilibrium are 4.8 $$\times$$ 10-2 and 1...
When rain is accompanied by a thunderstorm, the collected rain water will have a pH value
1 M NaCL and 1 M HCL are present in an aqueous solution. The solution is
Let the solubility of an aqueous solution of Mg(OH)2 be x then its Ksp is
Species acting as both Bronsted acid and base is
Change in volume of the system does not alter which of the following equilibria?
For the reaction CO (g) + (1/2) O2 (g) $$\leftrightharpoons$$ CO2 (g), Kp/Kc is
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